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Helix‐Sense‐Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles
Author(s) -
Luo Xiaofeng,
Deng Jianping,
Yang Wantai
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006658
Subject(s) - polymerization , micelle , helix (gastropod) , norbornadiene , polymer , polymer chemistry , acetylene , materials science , sense (electronics) , chemistry , organic chemistry , catalysis , ecology , snail , aqueous solution , biology
Hold that shape : An achiral acetylene underwent helix‐sense‐selective polymerization in chiral micelles consisting of [{(nbd)RhCl} 2 ] (nbd=2,5‐norbornadiene) and dodecylphenylalanine as a chiral emulsifier to produce optically active helical polymers and polymeric emulsions.