A Molecular Capsule Network: Guest Encapsulation and Control of Diels–Alder Reactivity | Zendy

Inokuma Yasuhide | Zendy; Yoshioka Shota | Zendy; Fujita Makoto | Zendy

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A Molecular Capsule Network: Guest Encapsulation and Control of Diels–Alder Reactivity

Author(s) -

Inokuma Yasuhide,

Yoshioka Shota,

Fujita Makoto

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004781

Subject(s) - cyclopentadiene , monomer , capsule , encapsulation (networking) , molecule , diels–alder reaction , polymer , chemistry , computer science , materials science , nanotechnology , organic chemistry , computer network , catalysis , biology , botany

The time capsule : A variety of guest molecules are stably trapped in networked coordination capsules up to 200 °C, which is above the boiling points of the guests. Networked capsules provide a distinctly different environment in the crystal form relative to that of pores, and are suitable for storing reactive molecules: Cyclopentadiene remains a monomer within the capsule even after heating, whereas dimerization through a Diels–Alder reaction takes place within the pore.

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