New Thermo‐Response Dyes: Coloration by the Claisen Rearrangement and Intramolecular Acid–Base Reaction | Zendy

Inouye Masahiko | Zendy; Tsuchiya Kikuo | Zendy; Kitao Teijiro | Zendy

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New Thermo‐Response Dyes: Coloration by the Claisen Rearrangement and Intramolecular Acid–Base Reaction

Author(s) -

Inouye Masahiko,

Tsuchiya Kikuo,

Kitao Teijiro

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199202041

Subject(s) - intramolecular force , claisen rearrangement , phenol , ether , chemistry , photochemistry , lactone , proton , carroll rearrangement , aryl , colored , base (topology) , medicinal chemistry , organic chemistry , materials science , physics , alkyl , quantum mechanics , composite material , mathematical analysis , mathematics

Applications in information storage and in thermally activated recording systems are anticipated for the novel allyl aryl ether 1 . At 180°C 1 rearranges to phenol lactone 2 , which in turn undergoes intramolecular proton migration to provide colored 3 .

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