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Early Members of a Homologous Series Based on Linked GeM 2 Triangles, (MCo, Fe): Structures of [Ge 2 Co 4 Fe 2 (CO) 21 ] and [Ge 3 Co 8 (CO) 26 ]
Author(s) -
Anema Skelte G.,
Mackay Kenneth M.,
McLeod Laurie C.,
Nicholson Brian K.,
Whittaker Jan M.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198607591
Subject(s) - homologous series , series (stratigraphy) , crystallography , combinatorics , mathematics , materials science , chemistry , geology , paleontology
Two and three fused spiropentane‐like structural units are present in the title compounds 1 and 2 , respectively (CO groups omitted). These are the first crystallographically confirmed examples for such extended structures formed from M'M 2 triangles.