Premium
The First [2.1] Phane: a New Helical Molecular Skeleton
Author(s) -
Duchêne KarlHeinz,
Vögtle Fritz
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198508851
Subject(s) - skeleton (computer programming) , enantiomer , chemistry , stereochemistry , anatomy , biology
The [2.1]phane 1 is rigidly twisted and therefore helical ; it is the [m.n]phane with the shortest bridges so far. Its synthesis was carried out in six steps. 1 could be separated into its enantiomers, which are stable up to 200°C.