Oxidation Reactions with “Naked” Permanganate Ions under Aprotic Conditions | Zendy

Bock Hans | Zendy; Jaculi Dieter | Zendy

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Oxidation Reactions with “Naked” Permanganate Ions under Aprotic Conditions

Author(s) -

Bock Hans,

Jaculi Dieter

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403051

Subject(s) - cyclic voltammetry , chemistry , anhydrous , permanganate , ion , inorganic chemistry , semiquinone , redox , photochemistry , spectroscopy , metal ions in aqueous solution , metal , electrochemistry , organic chemistry , electrode , physics , quantum mechanics

The one‐electron reduction of MnO 4 ⊖to MnO 4 2⊖can be achieved in anhydrous medium with dialkali‐metal catecholates 1 in presence of crown ethers. The semiquinone radical anion 2 formed in the reaction was detected, inter alia, by ENDOR spectroscopy and cyclic voltammetry (M Li, Na, K).

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