[2.2.2.2](1,2,4,5)Cyclophane Quinhydrone—A Donor‐Acceptor Cyclophane with an Extremely Short Transannular Distance | Zendy

Staab Heinz A. | Zendy; Schwendemann Volker | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

[2.2.2.2](1,2,4,5)Cyclophane Quinhydrone—A Donor‐Acceptor Cyclophane with an Extremely Short Transannular Distance

Author(s) -

Staab Heinz A.,

Schwendemann Volker

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197807561

Subject(s) - cyclophane , intramolecular force , quinhydrone electrode , acceptor , chemistry , ring (chemistry) , stereochemistry , crystallography , physics , crystal structure , organic chemistry , electrode , working electrode , electrolyte , condensed matter physics

The new intramolecular quinhydrone (1) exhibits an extremely short distance between the donor and the acceptor: the planes of the bridged ring C atoms are only 2.67 Å apart. Surprisingly, the wavelength and line width of the CT band of (1) are almost the same as those of the pseudogeminal [2.2]paracyclophane quinhydrone.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research