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Methylenesulfur Tetrafluoride H 2 CSF 4
Author(s) -
Kleemann Gert,
Seppelt Konrad
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197805161
Subject(s) - pseudorotation , carbene , chemistry , tetrafluoride , diazirine , computational chemistry , stereochemistry , organic chemistry , analytical chemistry (journal) , molecule , catalysis
The new pentacoordinated species H 2 CSF 4 , a gas stable up to at least 100°C, is not an ylide, but instead shows carbene‐type reactions. The 19 F‐ and 1 H‐NMR spectra are compatible with a Berry pseudorotation.
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