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Geometrical Dependence of [2π+2σ]Photocycloaddition
Author(s) -
Prinzbach Horst,
Sedelmeier Gottfried,
Martin HansDieter
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701031
Subject(s) - orientation (vector space) , atomic orbital , chemistry , computational chemistry , materials science , physics , mathematics , geometry , quantum mechanics , electron
The correlation between photochemical behavior and the orientation of bonding orbitals has been examined for several examples. Thus (1) reacts to give (2) and (3) , whereas (4) fails to give a cycloadduct but forms only the hydrogenated compound along with polymeric products.
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