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Enhancement of the Thermoelectric Performance of Polycrystalline In 4 Se 2.5 by Copper Intercalation and Bromine Substitution
Author(s) -
Luo Yubo,
Yang Junyou,
Li Gen,
Liu Ming,
Xiao Ye,
Fu Liangwei,
Li Weixin,
Zhu Pinwen,
Peng Jiangying,
Gao Sheng,
Zhang Jiaqi
Publication year - 2014
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201300599
Subject(s) - materials science , crystallite , substitution (logic) , thermoelectric effect , intercalation (chemistry) , bromine , thermoelectric materials , doping , tellurium , copper , nanoparticle , nanotechnology , computer science , optoelectronics , inorganic chemistry , thermal conductivity , thermodynamics , metallurgy , physics , chemistry , composite material , programming language
An effective approach to enhance the thermoelectric performance (ZT) of polycrystalline In 4 Se 3 based samples by crystallographic and microstructural engineering is proposed and demonstrated. Cu intercalation, Br substitution at selenium sites, and incorporation of dispersed hierarchical nanoparticles are discussed. An improved ZT of 1.1 at 723 K is achieved in CuBr 2 doped In 4 Se 2.5 .
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