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Lithium/Sulfide All‐Solid‐State Batteries using Sulfide Electrolytes
Author(s) -
Wu Jinghua,
Liu Sufu,
Han Fudong,
Yao Xiayin,
Wang Chunsheng
Publication year - 2021
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202000751
Subject(s) - electrolyte , sulfide , electrochemical window , materials science , electrochemistry , ionic conductivity , fast ion conductor , inorganic chemistry , conductivity , lithium (medication) , electrode , chemical engineering , chemistry , metallurgy , medicine , endocrinology , engineering
Abstract All‐solid‐state lithium batteries (ASSLBs) are considered as the next generation electrochemical energy storage devices because of their high safety and energy density, simple packaging, and wide operable temperature range. The critical component in ASSLBs is the solid‐state electrolyte. Among all solid‐state electrolytes, the sulfide electrolytes have the highest ionic conductivity and favorable interface compatibility with sulfur‐based cathodes. The ionic conductivity of sulfide electrolytes is comparable with or even higher than that of the commercial organic liquid electrolytes. However, several critical challenges for sulfide electrolytes still remain to be solved, including their narrow electrochemical stability window, the unstable interface between the electrolyte and the electrodes, as well as lithium dendrite formation in the electrolytes. Herein, the emerging sulfide electrolytes and preparation methods are reviewed. In particular, the required properties of the sulfide electrolytes, such as the electrochemical stabilities of the electrolytes and the compatible electrode/electrolyte interfaces are highlighted. The opportunities for sulfide‐based ASSLBs are also discussed.