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Hydrogen‐bonded pseudopolyrotaxanes
Author(s) -
Asakawa Masumi,
Ashton Peter R.,
Hayes Wayne,
Stoddart J. Fraser,
Brown George R.,
Menzer Stephan,
White Andrew J. P.,
Williams David J.
Publication year - 1996
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.19960080105
Subject(s) - supramolecular chemistry , stacking , crystal engineering , materials science , nanometre , hydrogen bond , monomer , nanotechnology , self assembly , supramolecular assembly , crystallography , crystal structure , polymer , molecule , organic chemistry , chemistry , composite material
That supramolecular order on the nanometer scale in the crystalline state can be created by using both π–π stacking and hydrogen bonding interactions marks a significant development in the fields of crystal engineering and supramolecular chemistry. The design and construction of pseudorotaxane monomers (see figure) via self‐assembly is described, which are then further assembled to form linear pseudopolyrotaxane columns.