Decamethylmanganocenium tetracyanoethenide, [Mn(C 5 Me 5 ) 2 ] ⊙⊙⊕  [TCNE] ⊙⊖ —a molecular ferromagnet with an 8.8 K  T c | Zendy

Miller Joel S. | Zendy; Dixon David A. | Zendy; McLean R. Scott. | Zendy; Groski David M. | Zendy; Flippen Richard B. | Zendy; Manriquez Juan M. | Zendy; Yee Gordon T. | Zendy; Narayan K. S. | Zendy; Epstein Arthur J. | Zendy

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Decamethylmanganocenium tetracyanoethenide, [Mn(C 5 Me 5 ) 2 ] ⊙⊙⊕ [TCNE] ⊙⊖ —a molecular ferromagnet with an 8.8 K T c

Author(s) -

Miller Joel S.,

Dixon David A.,

McLean R. Scott.,

Groski David M.,

Flippen Richard B.,

Manriquez Juan M.,

Yee Gordon T.,

Narayan K. S.,

Epstein Arthur J.

Publication year - 1991

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.19910030609

Subject(s) - tetracyanoethylene , isostructural , ferromagnetism , materials science , crystallography , curie temperature , singlet state , magnetic susceptibility , crystal structure , condensed matter physics , atomic physics , physics , chemistry , photochemistry , excited state

Communication: Triplet electron‐transfer salts are predicted to exhibit bulk ferromagnetic behavior at higher temperatures than their singlet analogues. To test this expected trend, the title compound, which is isostructural with [FeCp * 2 ] ⊙⊕ [TCNE] ⊙⊖ (Cp * = pentamethylcyloopentadienide; TCNE = tetracyanoethylene) which exhibits a Curie temperature, T c , of 4.8 K has been synthesized. The synthesis and magnetic characterization of the new compound, which is found to have a T c of 8.8 K, are reported.

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