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Surface Recognition of Dipolar Molecules Entering Channels of the Organic Zeolite Tris( o ‐phenylenedioxy)cyclotriphosphazene
Author(s) -
Hertzsch T.,
Kluge S.,
Weber E.,
Budde F.,
Hulliger J.
Publication year - 2001
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/1521-4095(200112)13:24<1864::aid-adma1864>3.0.co;2-o
Subject(s) - molecule , zeolite , tris , materials science , polar , dipole , monolayer , organic molecules , surface (topology) , chemical polarity , chemical engineering , polymer chemistry , crystallography , chemistry , nanotechnology , organic chemistry , catalysis , physics , biochemistry , geometry , mathematics , engineering , astronomy
Macroscopically polar crystals of an organic zeolite , tris( o ‐phenylenedioxy)cyclotriphosphazene, are obtained by partial guest exchange of included THF molecules with nonlinear optical molecules, which enter the channels via a mechanism of surface recognition (4‐amino‐4′‐nitrobiphenyl partially (left) and fully (right) stained crystals are shown in the Figure).
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