Control of the radical polymerization by 2,2,15,15‐tetramethyl‐1‐aza‐4,7,10,13‐tetraoxacyclopentadecan‐1‐oxyl and its sodium salt | Zendy

Olive Gilles | Zendy; Rozanska Xavier | Zendy; Smulders Wilfred | Zendy; Jacques Alain | Zendy; German Anton | Zendy

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Control of the radical polymerization by 2,2,15,15‐tetramethyl‐1‐aza‐4,7,10,13‐tetraoxacyclopentadecan‐1‐oxyl and its sodium salt

Author(s) -

Olive Gilles,

Rozanska Xavier,

Smulders Wilfred,

Jacques Alain,

German Anton

Publication year - 2002

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/1521-3935(200208)203:12<1790::aid-macp1790>3.0.co;2-f

Subject(s) - miniemulsion , polymerization , nitroxide mediated radical polymerization , styrene , polymer chemistry , chemistry , radical polymerization , sodium , salt (chemistry) , sodium salt , copolymer , organic chemistry , inorganic chemistry , polymer

The control of the radical polymerization of styrene by 2,2,15,15‐tetramethyl‐1‐aza‐4,7,10,13‐tetraoxacyclopentadecan‐1‐oxyl is reported here in bulk at 90 °C, 120 °C and in miniemulsion. Similarly, the control by its sodium complex is reported in bulk at 90 °C.M n vs. conversion for 3 , 3Na , and TEMPO.

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