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Functionalized Tellurium( II ) Thiolates: Tellurium Bis(2‐hydroxyethanethiolate) Hydrate, the First H 2 O–Te II Complex
Author(s) -
Fleischer Holger,
Schollmeyer Dieter
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001016)39:20<3705::aid-anie3705>3.0.co;2-y
Subject(s) - tellurium , hydrate , chemistry , inorganic chemistry , organic chemistry
Photochemically labile Te(CH 2 CH 2 OH) 2 is the first tellurium( II ) thiolate with functionalized side chains. Its H 2 O complex, Te(CH 2 CH 2 OH) 2 ⋅H 2 O (see structure), is stabilized in the solid state by short O−H⋅⋅⋅S hydrogen bonds.