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Bis‐vinylogous Corrole: The First Expanded Corrole
Author(s) -
Paolesse Roberto,
Khoury Richard G.,
Della Sala Fabio,
Di Natale Corrado,
Sagone Francesco,
Smith Kevin M.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990903)38:17<2577::aid-anie2577>3.0.co;2-g
Subject(s) - corrole , chemistry , salt (chemistry) , hydrogen bond , solid state , absorption (acoustics) , crystallography , molecule , photochemistry , materials science , organic chemistry , composite material
Abstract A dimeric structure that is held together by hydrogen bonds and is stable in solution is adopted by the hydrochloride salt of the expanded corrole shown. The synthesis, X‐ray structure, and NMR and electronic absorption spectra of the new species all confirm the structural assignment in solution and in the solid state.