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[M 3 V 18 O 42 (H 2 O) 12 (XO 4 )]⋅24 H 2 O (M=Fe, Co; X=V, S): Metal Oxide Based Framework Materials Composed of Polyoxovanadate Clusters
Author(s) -
Khan M. Ishaque,
Yohannes Elizabeth,
Doedens Robert J.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990503)38:9<1292::aid-anie1292>3.0.co;2-2
Subject(s) - oxide , metal , materials science , crystallography , nanotechnology , inorganic chemistry , chemistry , metallurgy
Abstract New framework materials composed of well‐defined vanadium oxide clusters were prepared by low‐temperature reactions and characterized by X‐ray crystal structure analysis. The structures of these solids contain {V 18 O 42 } cages linked into two interpenetrating three‐dimensional networks by bridging {M(H 2 O) 4 } groups (M=Fe II , Co II ; see picture).