Open AccessDesulfurization reaction of cis ‐1,2‐diphenyl‐3‐aryl‐1,4,2‐diazaphospholidin‐5‐thione‐2‐oxides utilizing an Ag + −H 2 O or ROH system
Author(s) -
Zhou Jia,
Chen Ruyu
Publication year - 1998
Publication title -
heteroatom chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.283
H-Index - 42
eISSN - 1098-1071
pISSN - 1042-7163
DOI - 10.1002/(sici)1098-1071(1998)9:6<585::aid-hc10>3.0.co;2-n
Subject(s) - chemistry , flue gas desulfurization , heteroatom , ring (chemistry) , aryl , medicinal chemistry , polymer chemistry , organic chemistry , combinatorial chemistry , alkyl
Abstract A desulfurization reaction of the title compounds, as cyclic substrates, utilizing an Ag + −H 2 O or ROH system, is described in this article. The diastereoisomerism of ring‐opening products and the possible reaction mechanism are also discussed. Themolecular structure of α‐(3‐phenylureido)‐α‐(2,4‐dichlorophenyl)methylphenylphosphinic acid ( 4a ) was determined by X‐ray diffraction. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9: 585–590, 1998