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Rod‐climbing in a particle‐suspended polymeric liquid
Author(s) -
Choi Hyoung J.,
Sim In S.,
Lim Sung T.,
Jhon Myung S.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(20000124)75:4<572::aid-app13>3.0.co;2-v
Subject(s) - kaolinite , rheology , materials science , particle (ecology) , climbing , particle size , polymer chemistry , composite material , analytical chemistry (journal) , chemistry , mineralogy , chromatography , geology , oceanography , archaeology , history
The rod‐climbing experiment and its relationship to the first normal stress difference of kaolinite particle‐suspended polyisobutylene (PIB)/polybutene (PB) systems possessing Boger fluid characteristics (no shear‐thinning and highly elastic) were investigated. The rod‐climbing constants of the kaolinite/PIB/PB system obtained from the second‐order fluid model increased with particle concentration and PIB molecular weight, indicating that the elasticity of the PIB/PB increases as kaolinite particle concentration increases. The first normal stress difference obtained from the rod‐climbing constant is also correlated with that measured value using RMS‐800, a mechanical spectrometer, for the particle‐suspended PIB/PB system. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 572–575, 2000

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