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Density and ultrasonic velocity have been measured in the binary liquid mixtures of methyl acetate (MA) and ethyl acetate (EA) in 2-methoxyethanol (2ME) over the temperature range from 303.15 to 323.15 K. The measured data are used to compute the excess thermodynamic parameters namely excess adiabatic compressibility (βs E ), excess intermolecular free length (Lf E ) and excess molar volume (V E ). A plot of these excess thermodynamic parameters against the mole fraction of methyl acetate and ethyl acetate over the entire composition range shows a negative deviation indicating a strong interaction between the component molecules of liquid mixtures. The results are discussed in terms of formation of hydrogen bonding between the component molecules of the liquid mixtures.

Thermoacoustical studies on the Binary mixtures of Methyl and Ethyl acetate (MA & EA) in 2-Methoxyethanol (2ME) at different temperatures