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A novel monomeric UV-absorber was prepared by the reaction of 2,4-dihydroxybenzophenone with N-4-chlorocarbonylphenylmaleimide in the presence of triethylamine. This reactive maleimide was grafted onto polypropylene (PP) by the thermal melt-processing in a mini-max-moulder. IR spectroscopic method was used for the quantitative determination of the extent of grafting of monomeric maleimide. To find the optimal reaction conditions, the dependence of reaction temperature and time and the concentration of monomeric UV-absorber was investigated on the grafting yields. The photooxidative effect of the grafted PP was evaluated in the weatherometer comparing to the PP mixed with UVabsorbers using the carbonyl index of IR spectrum. The grafted PP showed an excellent anti-photooxidative effect.

Thermal Melt Grafting of Maleimides Having UV-absorber onto Polypropylene