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peptaibols in microbial culture extracts3~5). Here we report the isolation and structure elucidation of peptaibolin (1, Fig. 1) as an unusual representative of the peptaibol family of lipophilic antibiotics. 1 was disclosed in two fungal strains, Sepedonium sp. HKI-0117 and Sepedonium ampullosporum HKI-0053 coproducing the neuroleptic peptaibol-type antibiotic ampullosporin5). In contrast to the known peptaibols6), the compound 1 contains only five peptide bonds. However, it displays all of the structural features of the

Isolation and Structure of Peptaibolin, a New Peptaibol from Sepedonium Strains.