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The aim of this study was to confirm the feasibility of the electro-coagulation process as a pre-treatment for the membrane separation of anaerobic digestion effluents to minimize membrane fouling. The reduction of membrane fouling was evaluated according to the number of electrodes (immersed surface area of electrodes), current density and contact time. In the case of the small surface area of electrodes, the increased electric field strength resulted in a soluble COD increase due to the destruction of the microbial flocs and/or cells, whereas large changes in the soluble COD were not observed in the case of the high surface area of electrodes. On the other hand, the T-P concentration decreased as a result of the precipitation of aluminum ions and phosphates. The membrane permeation flux increased and the fouling resistance (Rc+Rf) decreased with increasing electric current density. Although the particle size of the anaerobic digestion effluent increased slightly, it was not related directly to the reduced fouling phenomena. The main mechanism for the enhanced flux was attributed to the inorganic particulate produced during electrocoagulation, such as , which acted as a dynamic membrane deposited on the membrane surface.

Application of electro-coagulation for the pretreatment of membrane separation of anaerobic digestion effluents