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Smog chamber/FTIR techniques were used to study the products and mechanismsof OH radical and Cl atom initiated oxidation of trans-CF3CH=CHF in 700 Torrof N2/O2 diluent at 295±1 K. Hydroxyl radical initiatedoxidation leads to the formation of CF3CHO and HC(O)F in yields whichwere indistinguishable from 100% and were not dependent on the O2partial pressure. Chlorine atom initiated oxidation gives HC(O)F,CF3CHO, CF3C(O)Cl, and CF3C(O)CHFCl. The yields ofCF3C(O)Cl and CF3C(O)CHFCl increased at the expense of HC(O)F andCF3CHO as the O2 partial pressure was increased over the range5–700 Torr. The results are discussed with respect to the atmosphericchemistry and environmental impact of trans-CF3CH=CHF

atmospheric chemistry and physics

Atmospheric chemistry of trans-CF&amp;lt;sub&amp;gt;3&amp;lt;/sub&amp;gt;CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation