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ABSTRACT The reaction of 3,5-bis(bromomethyl)toluene with benzotriazole yields the bidentate ligand 3,5-bis(benzotriazol-1-ylmethyl)toluene (1) . This ligand reacts with [PdCl 2 (cod)] (cod = 1,5-cyclooctadiene) to give the complex [PdCl 2 {3,5-bis(benzotriazol-1-ylmethyl)tolyl}] (2) . These compounds were characterized by elemental analyses, mass spectra, and FTIR and NMR ( 1 H, 13 C) spectroscopies. The palladium(II) complex 2 shows high activity as catalyst for oxidative amination, involving allyl butyl ether and phthalimide as substrates and PhICl 2 as a stoichiometric oxidant. Keywords: Palladium complex; Bidentate nitrogen ligand; Aminopalladation, Oxidative aminatione-mail address: jmvalder@puc.cl 1. INTRODUCTION The syntheses of late transition metal complexes have received much attention due to their potential applications for olefin polymerization catalysis. 1,2 The discovery of a new class of catalysts based on Ni(II) or Pd(II) a-diimine compounds by Brookhartet al.

PALLADIUM COMPLEX BEARING 3,5-BIS(BENZOTRIAZOL-1-YLMETHYL)TOLUENE LIGAND CATALYZES OXIDATIVE AMINATION OF ALLYL BUTYL ETHER