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The detailed redox behaviour of copper-saccharin (Cu-sac) complex was examined using the cyclic voltammetric technique. It was found that the adsorption process suppresses the Faradaic process of the Cu-sac complex. The effect of the introduction of secondary ligands such as 1,10 -phenanthroline (phen), pyridine (py) and bypyridine (bp) on the redox behaviour of the Cu-sac complex in aqueous solution was studied where these ligands contribute on the charge-transfer kinetics of the complex. The heterogeneous charge transfer rate constants are found to follow the order Cu(NO 3 ) 2 > Cu-sac-bp > Cu-sac > Cu-sac-phen > Cu-sac-py.

Cyclic voltammetric study on the effect of the introduction of secondary ligands on the redox behaviour of the copper-saccharin complex