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Reactions of the ethoxysilyl and thiol groups of 6-(3-triethoxysilylpropylamino)-1,3,5-triazine-2,4-dithiol-monosodium salt (TES) with Ti, Al, Fe, and Sn metals were investigated. Metals and heating temperatures affect the reaction types of ethoxysilyl and thiol groups, following the ionization tendency series. The ethoxysilyl groups reacted with all three types of metals (series with high, moderate and low ionization tendencies). The thiol groups reacted with the Sn oxide films to produce Sn-S bonds. For Fe and Sn surfaces, SS groups were formed by the oxidation of thiol groups in air. For all metals used here, SOX groups were observed. Key-words: Metals, 6-(3-triethoxysilylpropylamino)-1,3,5-triazine-2,4-dithiol-monosodium salt, XPS surface analysis, Ionization tendency series Note J. Jpn. Soc. Colour Mater., 86〔1〕,8–11(2013)

Reaction of 6-(3-Triethoxysilylpropylamino)-1,3,5-Triazine-2,4-Dithiol-Monosodium Salt with Metal Surfaces