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N-Acyl threonine isopeptides undergo acyl transfer in chemical ligations via 5-, 8-, 9and 10membered cyclic transition states to yield natural peptides, representing the first examples of successful isopeptide ligations from N-acyl threonine units.

Ligations of O-acyl threonine units to give native peptides via 5-, 8-, 9- and 10-membered cyclic transition states