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An efficient protocol for the oxidation of alcohols to carbonyl compounds with molecular iodine and potassium tert -butoxide is described. Various primary and secondary alcohols were converted to the corresponding aldehydes and ketones in high yields. The oxidation of 2- phenylethanol produced an "abnormal" acetalic ketone. The readily availability of starting materials, convenient synthetic procedure, operational simplicity, mild reaction conditions, and high yields makes this protocol a competitive alternative in the synthesis of ynones and ketones as well as aryl aldehydes.

Oxidation of alcohols to carbonyl compounds with molecular iodine in the presence of potassium tert-butoxide