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Regioand stereoselective Diels-Alder reaction of diphenyl 5-methylhexa-1,3,4-trien-3-yl phosphine oxide 1 with N-(4-substituted-phenyl)maleimides or maleic anhydride and the formation of a series of the 5-(diphenylphosphinoyl)-4-isopropylidene-2-(4-substituted-phenyl)3a,4,7,7a-tetrahydroisoindole-1,3-diones 5a-g and the 5-(diphenylphosphinoyl)-4isopropylidene-3a,4,7,7a-tetrahydroisobenzofuran-1,3-dione 3 respectively is described.

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Regio- and stereoselective Diels-Alder reaction of diphenyl 5-methylhexa-1,3,4-trien-3-yl phosphine oxide with N-(4-substituted-phenyl)maleimides and maleic anhydride