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This research was supported by the Ministerio de Ciencia e Innovacion (Projects CTQ2007-62771/BQU, CTQ2007-65218/BQU and Consolider Ingenio 2010 CSD2007-00006), the Generalitat Valenciana (Project PROMETEO/2009/039, FEDER) and the University of Alicante (UA).

(S)-Binam-L-prolinamide as organocatalyst for the enantioselective conjugate addition of α-alkoxyketones to β-nitrostyrene derivatives