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The catalytic activity of a benzimidazole-oxime Pd(II)-complex towards Suzuki and Heck C-C cross-coupling reactions of activated and deactivated aryl- and heteroaryl bromides under microwave irradiation as well as thermal heating using water as a green solvent was evaluated. The turnover frequency reached 420,000 under microwave condition.

Microwave-assisted C-C cross-coupling reactions of aryl and heteroaryl halides in water