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The synthesis of morphine (1) and pancratistatin (2) have been the subject of intense effort by the synthetic community for many years. Our focus on the total synthesis of these challenging targets resulted in several generations of approaches that combine enzymatic transformations with traditional synthetic protocols in order to provide for maximum efficiency and brevity in attaining the targets. O NMe O H O H O O NH O H OH OH O OH

Chemoenzymatic synthesis of complex natural and unnatural products: morphine, pancratistatin, and their analogs