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A stereoselective route to the synthesis of γ -lactone fused cyclopentenes, the core structure of the marine eicosanoids bacillariolides, is described. The key step involves ring closing metathesis of 1,-6-diene built from D-mannitol to construct the cyclopentene unit in enantiomerically pure form.

An asymmetric route to the construction of the bicyclic framework of marine eicosanoids bacillariolides