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InCl3 (2 mol%) in combination with Me3SiCl (20 mol%) efficiently catalyze Ferrier rearrangement in a variety of glycal derivatives with different silyl nucleophiles to afford the corresponding Cpseudoglycals or unsaturated pyrans in nearly quantitative yields. The stereoselectivities of the C-glycosides are good to excellent in favor of the α-anomers. A stoichiometric amount of InCl3 is necessary for similar transformations in the absence of Me3SiCl. The InCl3 can be recovered and reused without any loss of its activity.

Synergistic enhancement of catalytic activity of InCl3 - Me3SiCl combination towards carbon Ferrier rearrangement in glycal derivatives