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The structure of the series of new thiazolo[3,4-a]quinoxalines are described. X-ray crystal structure determination reveals significant differences in supramolecular structures of substituted thiazolo[3,4-a]quinoxalines which depends on whether the solvent molecules are involved in the crystal formation. It was shown that the separation of hydrophilic and hydrophobic regions observed in the crystals might be considered in the terms of the theory of microphase separation in block polymers. The type of supramolecular structures was found to depend on the volume ratio of hydrophilic-hydrophobic molecular fragments.

The supramolecular structure of thiazolo[3,4-a]quinoxalines: hydrogen bonding and amphiphilic properties