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Reactions of diphenylvinylsulfonium triflates with primary amines and imides afforded 2- arylaziridines and α-imidostyrenes, respectively. These products were also obtained from styrenes in one vessel without isolation of the intermediate sulfonium salts. In addition, 1,1- disubstituted and trisubstituted alkenes were converted into allylamines via isomerization of initially formed vinylsulfonium salts to allylsulfonium salts in the presence of primary or secondary amines.

New methods for the preparations of 2-aryl aziridines, α-imido styrenes, and allyl amines from olefins via diphenylvinylsulfonium triflates