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A range of imidazo-1,2,3-triazoles were synthesised by the 1,3-dipolar cycloaddition of triazolium-1-imides with N-sulfonyl imines. Oxazolo-1,2,3-triazoles were identified as side products of this reaction. Benzyne was also used as a 1,3-dipolarophile in the cycloaddition reaction, resulting in a range of tricyclic triazoloindoles.

Novel cycloadducts from the 1,3-dipolar cycloaddition reactions of triazolium-1-imide 1,3-dipoles