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The reductive Heck-type hydroarylation reactions of hetero-atom containing norbornene derivatives catalyzed by palladium complexes of chiral quinolinyl-oxazolines were examined and moderate to good chiral inductions and chemical yields were achieved. Using this new method N-protected epibatidine was readily synthesized.

Asymmetric hydroarylation of hetero-atom containing norbornene derivatives and enantioselective synthesis of analogs of epibatidine