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There has been a revival of interest in the chemistry of cyclitols in the recent past due to the discovery of phosphoinositol based signal transduction mechanisms in eukaryotic systems. Traditionally, synthesis of inositol derivatives involved the protection of its hydroxyl groups as the corresponding ketals. However, recently orthoesters of myo-inositol have emerged as convenient intermediates for the synthesis of inositol derivatives. The present account describes recent progress in the chemistry related to myo-inositol orthoesters.

Regioselective protection of myo-inositol orthoesters – recent developments