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Dimethyl N-(2,2-diethoxyethyl)-iminodithiocarbamate 3 is shown to react with primary amines in boiling acetic acid to afford 1-substituted-2-methylthioimidazoles in 81-87% overall yields.

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Reaction of dimethyl N-(2,2-diethoxyethyl)­iminodithiocarbamate with primary amines. A new general appraoch for the synthesis of 1-substituted 2-methylthio­imidazoles

Reaction of dimethyl N-(2,2-diethoxyethyl)­iminodithiocarbamate with primary amines. A new general appraoch for the synthesis of 1-substituted 2-methylthio­imidazoles

Reaction of dimethyl N-(2,2-diethoxyethyl)iminodithiocarbamate with primary amines. A new general appraoch for the synthesis of 1-substituted 2-methylthioimidazoles