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Kinetic studies of bromofunctionalisation of cycloalkenes with N-bromosuccinimide (NBS) in acetonitrile-water under various conditions were carried out. Reaction with bicyclo(2,2,1)heptene (norbornene) in acetonitrile-water solution gave three main products: 2-exo-hydroxy-7-syn- bromo norbornane, 2-exo- hydroxy-7-anti-bromo norbornane and bromonortricyclane in 5:1:1 ratio. The course of the reaction obeys a simple rate equation:

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The chemistry of organohalogenic molecules. Part 172. Kinetic studies of bromine transfer from N-bromo-succinimide to norbornene under protic conditions