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A simplified protocol of dry-state adsorption condition (DSAC) Pauson-Khand cyclizations for the preparation of the title compounds and the synthesis of a variety of perhydro- cyclopenta(c)pyrrolones, are reported. In one case the formation of a monocyclic compound was observed in varying amounts depending on the reaction atmosphere.

Application of dry-state adsorption condition (DSAC) Pauson-Khand cyclization for the synthesis of perhydrocyclopenta[c]pyrroles