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The preparation and application of a new reagent for stereoselective deuterium addition to substituted cyclohexanones is described affording cyclohexanols with axial hydroxy group with high stereoselectivity. The results are compared with other established reduction methods.

Lithium tri-sec-butylborodeuteride: a new reagent for the stereoselective deuterium addition to cyclohexanones with single chair conformations