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Treatment of the stable analogue of a 1,5-anthraquinone, namely, anthra(1,9-cd:5,10- c,d,)bisisoxazole, with primary and secondary amines in an inert atmosphere leads to the cleavage of one of the isoxazole moieties to afford 3(5)-alkylamino-7-amino-6H-6- oxoanthra(1,9-cd)isoxazoles. However, amination in the presence of air leads to (5)-alkylamino- anthra(1,9-cd:5,10-c,d,)bisisoxazole without cleavage of the isoxazole moiety.

Amination of anthra[1,9-cd:5,10-c,d,]bisisoxazole by alkylamines