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A Si/SiOC/graphite composite structure with high efficiency and long-term cycling stability was synthesized using a cost-effective method. In this structure, a SiOC network with good chemical stability acts as a skeleton to support and segregate Si nanostructures. The graphite incorporated in the Si/SiOC composite is used as a conductive material to enhance the electrical conductivity. Such Si/SiOC/graphite composite anodes show excellent cycling stability, with a specific capacity of similar to 637.3 mAh.g(-1) and similar to 86% capacity retention over 100 cycles at a rate of 0.3C. The design of this new structure has the potential to provide a basis for the development of other functional composite materials.

Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials