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In this work, we study three aluminum oxides (alpha, gamma, boehmite) and various oxidized metallic aluminum powders to observe their dehydration and decomposition behavior using in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and scanning electron microscopy (SEM). We find that a temperature increase to the aluminum oxides (aluminas) reduces physically adsorbed water molecules to reveal the presence of hydroxyl groups. All three aluminas contained bridged hydroxyls located at 3670 cm−1; we found additional surface hydroxyls, which varied based on the oxidation state of the aluminum atom. Oxidized metallic aluminum powders that were aged resulted in similar behavior; however, the results differed depending on the method of aging. We find that naturally aged aluminum (NA-Al) powders with heavy oxidation in the form of the tri-hydroxide decomposed and did not reveal any detectable surface hydroxyl peaks. When aged using artificial methods (AA-Al), we find both surface hydroxyls, including bridged hydroxyls at 3670, 3700, and 3730 cm−1, and a remaining boehmite-like surface. These results show that metallic aluminum powders can be tailored for specific applications, regardless of age. It also elucidates different ways to pre-process the powders to control the surface oxide layer, corroborated by comparison with the models oxides studied herein.

Infrared Spectroscopy Studies of Aluminum Oxide and Metallic Aluminum Powders, Part I: Thermal Dehydration and Decomposition