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The scope of this study is to elucidate the physical mechanisms influencing thetransient flow behavior of lubricating greases based on biogenic oleochemicals from apolarity point of view. This includes the mutually interacting influence of base oil polarityand thickening agents on the rheologically-measured mechanical structural degradation intransient shear flow. Due to the high temperature dependence of Keesom forces in thebackground of polar-active bond mechanisms, the analysis of the transient flow response asa function of temperature allows to attribute the observed influences to differences in baseoil polarity. In general, clay-thickened greases show a greater tendency to be rheologicallyinfluenced by base oil polarities than soap-thickened lubricating greases

Influence of Base Oil Polarity on the Transient Shear Flow of Biodegradable Lubricating Greases