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Tetra(phenylethynyl)tin reacts with aromatic aldehydes in the presence of a Lewis acid followed by the Oppenauer-type in situ oxidation of propargyl alcohols to give acetylenic ketones in a very good yield.

Oppenauer-type synthesis of &alpha;, &beta;-acetylenic ketones from tetra(phenylethynyl)tin and aromatic aldehydes

Oppenauer-type synthesis of α, β-acetylenic ketones from tetra(phenylethynyl)tin and aromatic aldehydes